The Earth's atmosphere is a layer of gases surrounding the planet Earth that is retained by the Earth's gravity. Dry air contains roughly (by molar content – equivalent to volume, for gases) 78.08% nitrogen, 20.95% oxygen, 0.93% argon, 0.038% carbon dioxide, and trace amounts of other gases; but air also contains a variable amount of water vapor, on average around 1%. This mixture of gases is commonly known as air. The atmosphere protects life on Earth by absorbing ultraviolet solar radiation, warming the surface through heat retention (greenhouse effect), and reducing temperature extremes between day and night.
There is no definite boundary between the atmosphere and outer space. It slowly becomes thinner and fades into space. Three quarters of the atmosphere's mass is within 11 km of the planetary surface. An altitude of 120 km (~75 miles or 400,000 ft) marks the boundary where atmospheric effects become noticeable during re-entry. The Kármán line, at 100 km (62 miles or 328,000 ft), is also frequently regarded as the boundary between atmosphere and outer space.
Composition
Filtered air includes at least trace amounts of ten (or more) of the chemical elements. Substantial amounts of argon, nitrogen, and oxygen are present as elementary gases, as well as hydrogen (and additional oxygen) in water vapor (H2O). Much smaller or trace amounts of elementary helium, hydrogen, iodine, krypton, neon, and xenon are also present, as well as carbon in carbon dioxide (CO2), methane (CH4), and carbon monoxide (CO). Many additional elements from natural sources may be present in tiny amounts in an unfiltered air sample, including contributions from dust, pollen and spores, sea spray, vulcanism, and meteoroids. Various industrial pollutants are also now present in the air, such as chlorine (elementary or in compounds), fluorine (in compounds), elementary mercury, and sulfur (in compounds such as sulfur dioxide [SO2]).
| ppmv: parts per million by volume | |
| Gas | Volume |
|---|---|
| Nitrogen (N2) | 780,840 ppmv (78.084%) |
| Oxygen (O2) | 209,460 ppmv (20.946%) |
| Argon (Ar) | 9,340 ppmv (0.9340%) |
| Carbon dioxide (CO2) | 383 ppmv (0.0383%) |
| Neon (Ne) | 18.18 ppmv (0.001818%) |
| Helium (He) | 5.24 ppmv (0.000524%) |
| Methane (CH4) | 1.745 ppmv (0.0001745%) |
| Krypton (Kr) | 1.14 ppmv (0.000114%) |
| Hydrogen (H2) | 0.55 ppmv (0.000055%) |
| Not included in above dry atmosphere: | |
| Water vapor (H2O) | ~0.40% over full atmosphere, typically 1% to 4% near surface |
| Gas | Volume |
|---|---|
| nitrous oxide | 0.3 ppmv (0.00003%) |
| xenon | 0.09 ppmv (9x10-6%) |
| ozone | 0.0 to 0.07 ppmv (0%-7x10-6%) |
| nitrogen dioxide | 0.02 ppmv (2x10-6%) |
| iodine | 0.01 ppmv (1x10-6%) |
| carbon monoxide | trace |
| ammonia | trace |
ppmv
The composition figures above are by volume-fraction (V%), which for ideal gases is equal to mole-fraction (that is, the fraction of total molecules). Although the atmosphere is not an ideal gas, nonetheless the atmosphere behaves enough like an ideal gas that the volume-fraction is the same as the mole-fraction for the precision given.
By contrast, mass-fraction abundances of gases will differ from the volume values. The mean molar mass of air is 28.97 g/mol, while the molar mass of helium is 4.00, and krypton is 83.80. Thus helium is 5.2 ppm by volume-fraction, but 0.72 ppm by mass-fraction ([4/29] × 5.2 = 0.72), and krypton is 1.1 ppm by volume-fraction, but 3.2 ppm by mass-fraction ([84/29] × 1.1 = 3.2).
[edit] Heterosphere
Below the turbopause at an altitude of about 100 km (not far from the mesopause), the Earth's atmosphere has a more-or-less uniform composition (apart from water vapor) as described above; this constitutes the homosphere.[6] However, above about 100 km, the Earth's atmosphere begins to have a composition which varies with altitude. This is essentially because, in the absence of mixing, the density of a gas falls off exponentially with increasing altitude but at a rate which depends on the molar mass. Thus higher mass constituents, such as oxygen and nitrogen, fall off more quickly than lighter constituents such as helium, molecular hydrogen, and atomic hydrogen. Thus there is a layer, called the heterosphere, in which the earth's atmosphere has varying composition. As the altitude increases, the atmosphere is dominated successively by helium, molecular hydrogen, and atomic hydrogen. The precise altitude of the heterosphere and the layers it contains varies significantly with temperature.
In pre-history, the Sun's radiation caused a loss of the hydrogen, helium and other hydrogen-containing gases from early Earth, and Earth was devoid of an atmosphere. The first atmosphere was formed by outgassing of gases trapped in the interior of the early Earth, which still goes on today in volcanoes.[7]
[edit] Density and mass
The density of air at sea level is about 1.2 kg/m3 (1.2 g/L). Natural variations of the barometric pressure occur at any one altitude as a consequence of weather. This variation is relatively small for inhabited altitudes but much more pronounced in the outer atmosphere and space because of variable solar radiation.
The atmospheric density decreases as the altitude increases. This variation can be approximately modeled using the barometric formula. More sophisticated models are used by meteorologists and space agencies to predict weather and orbital decay of satellites.
The average mass of the atmosphere is about 5 quadrillion metric tons or 1/1,200,000 the mass of Earth. According to the National Center for Atmospheric Research, "The total mean mass of the atmosphere is 5.1480×1018 kg with an annual range due to water vapor of 1.2 or 1.5×1015 kg depending on whether surface pressure or water vapor data are used; somewhat smaller than the previous estimate. The mean mass of water vapor is estimated as 1.27×1016 kg and the dry air mass as 5.1352 ±0.0003×1018 kg."
Temperature and layers
The temperature of the Earth's atmosphere varies with altitude; the mathematical relationship between temperature and altitude varies among five different atmospheric layers (ordered highest to lowest, the ionosphere is part of the thermosphere):
- Exosphere: from 500 – 1000 km (300 – 600 mi) up to 10,000 km (6,000 mi), contain free-moving particles that may migrate into and out of the magnetosphere or the solar wind.
- Ionosphere: the part of the atmosphere that is ionized by solar radiation. It plays an important part in atmospheric electricity and forms the inner edge of the magnetosphere. It has practical importance because, among other functions, it influences radio propagation to distant places on the Earth. It is located in the thermosphere and is responsible for auroras.
- Thermosphere: from 80 – 85 km (265,000 – 285,000 ft) to 640+ km (400+ mi), temperature increasing with height.
- Mesosphere: From the Greek word "μέσος" meaning middle. The mesosphere extends from about 50 km (160,000 ft) to the range of 80 to 85 km (265,000 – 285,000 ft), temperature decreasing with height. This is also where most meteors burn up when entering the atmosphere.
- Stratosphere: From the Latin word "stratus" meaning spreading out. The stratosphere extends from the troposphere's 7 to 17 km (23,000 – 60,001 ft) range to about 51 km (160,001 ft). Temperature increases with height. The stratosphere contains the ozone layer, the part of the Earth's atmosphere which contains relatively high concentrations of ozone. "Relatively high" means a few parts per million—much higher than the concentrations in the lower atmosphere but still small compared to the main components of the atmosphere. It is mainly located in the lower portion of the stratosphere from approximately 15 to 35 km (50,000 – 116,000 ft) above Earth's surface, though the thickness varies seasonally and geographically.
- Troposphere: From the french word "τρέπω" meaning to turn or change. The troposphere is the lowest layer of the atmosphere; it begins at the surface and extends to between 7 km (23,000 ft) at the poles and 17 km (60,000 ft) at the equator, with some variation due to weather factors. The troposphere has a great deal of vertical mixing because of solar heating at the area. This heating cools air masses, which makes them less dense so they rise. When an air mass rises, the pressure upon it decreases so it expands, doing work against the opposing pressure of the surrounding air. To do work is to expend energy, so the temperature of the air mass decreases. As the temperature decreases, water vapor in the air mass may condense or solidify, releasing latent heat that further uplifts the air mass. This process determines the maximum rate of decline of temperature with height, called the adiabatic lapse rate. The troposphere contains roughly 80% of the total mass of the atmosphere. Fifty percent of the total mass of the atmosphere is located in the lower 5.6 km of the troposphere.
The average temperature of the atmosphere at the surface of Earth is 20 °C (60 °F)
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